Tricyclo[3.3.1.03,7]nonane-3,7-diyl bis(methanesulfonate)
نویسندگان
چکیده
The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane [maximum deviation 0.01 Å], resulting in an eclipsing conformation of the C-O bonds. The C-C bond of the quaternary C atoms is 1.597 (3) Å is considerably longer than the other C-C bonds of the mol-ecule.
منابع مشابه
Tricyclo[3.3.1.03,7]nonane-3,7-diyl bis(4-methylbenzenesulfonate)
The title compound, C23H26O6S2 was synthesized by esterification of tri-cyclo-[3.3.1.0(3,7)]nonane-3,7-diol with p-toluene-sulfonyl chloride. The mol-ecule has symmetry 2 and is situated on site 4e. The C-C bond length between the quartenary C atoms is 1.598 (2) Å, which is considerably longer than other C-C bonds in the mol-ecule. There are C-H⋯O inter-actions present in the structure. As a co...
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